Unusual Isotope Effect in the Reaction of Chlorosilylene with Trimethylsilane-1-d. Absolute Rate Studies and Quantum Chemical and Rice–Ramsperger–Kassel–Marcus Calculations Provide Strong Evidence for the Involvement of an Intermediate Complex-Reference-Cited by-同舟云学术

Unusual Isotope Effect in the Reaction of Chlorosilylene with Trimethylsilane-1-d. Absolute Rate Studies and Quantum Chemical and Rice–Ramsperger–Kassel–Marcus Calculations Provide Strong Evidence for the Involvement of an Intermediate Complex

Published:2012-06-14 Issue:25 Volume:134 Page:10493-10501
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Becerra Rosa¹,Boganov Sergey E.²,Egorov Mikhail P.²,Krylova Irina V.²,Promyslov Vladimir M.²,Walsh Robin³

Affiliation:

1. Instituto de Quimica-Fisica “Rocasolano”, Consejo Superior de Investigaciones Científicas (CSIC), C/Serrano 119, 28006 Madrid, Spain

2. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospekt 47, 119991 Moscow, Russian Federation

3. Department of Chemistry, University of Reading, Whiteknights, P.O. Box 224, Reading RG6 6AD, United Kingdom

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja301924b

Reference80 articles.

1. cLewis, E. S.InIsotopes in Organic Chemistry;Buncel, E. and Lee, C. C., Eds.Elsevier:New York, 1976; Vol.2, Chapter 4, p127.

2. Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms

3. The Relative Reaction Velocities of Isotopic Molecules

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