Electrophilic Reactivity of the α,α-Dimethylbenzyl (Cumyl) Cation
Author:
Affiliation:
1. Department Chemie und Biochemie, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13 (Haus F), 81377 München, Germany
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ma9024569
Reference78 articles.
1. Rates of Solvolysis of Substituted Phenyldimethylcarbinyl Chlorides in Methyl, Ethyl and Isopropyl Alcohols. Influence of the Solvent on the Value of the Electrophilic Substituent Constant1,2
2. Electronic and steric effects on the solvation at the transition state in the solvolysis of some tertiary benzylic chlorides
3. Kinetic evidence for the solvent intervention in the solvolysis of 2-aryl-2-propyl p-nitrobenzoates. Electronic and steric effects
4. Solvolysis of 2-aryl-2-propyl benzoates. Validity of the assumption of constant p-nitrobenzoate/benzoate rate ratios
5. Structural effects in solvolytic reactions. 18. Relative electron releasing properties of methyl, phenyl, and cyclopropyl groups to the electron deficient center as indicated by solvolysis. Study of carbon-13 chemical shifts as a basis for establishing the electron densities in carbonium ions
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