1. A few selected examples. (a) Hydrogenations of emulsified substrates in water: Abu-Reziq, R.; Blum, J.; Avnir, D.Chem. Eur. J.2004,10, 958. (b) Enzymatic esterifications in organic solvent: Reetz, M. T.; Tielmann, P.; Wiesenhofer, W.; Konen, W.; Zonta, A.Adv. Synth. Catal.2003,345,717. (c) Aerobic oxidations in supercritical carbon dioxide: Campestrini, S.; Carraro, M.; Ciriminna, R.; Pagliaro, M.; Tonellato, U.Adv. Synth. Catal.2004,346, 231. (d) Epoxidations with H2O2: Campestrini, S.; Donoli, A.; Tonellato, U.Lett. Org. Chem.2004,1,125. (e) Biocatalytic conversions: Gill, I.; Ballesteros, A.Trends Biotechnol.2000,18, 282. (f) Pandey, P. C.; Upadhyay, S.; Sharma, S.Electroanal.2003,15, 1115. For a recent review on the use of ORMOSIL in catalysis, see: (g) Ciriminna, R.; Pagliaro, M.Curr.Org. Chem.2004,8, 1851. An account on the impressive achievements made possible by the chemistry of doped organo-silica is reported in: (h) Avnir, D.; Klein, L. C.; Levy, D.; Schubert, U.; Wojcik, A. B. Organo-Silica Sol−Gel Materials. InThe Chemistry of Organic Silicon Compounds, Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; pp 2317−2362.
2. Metabolizing enzyme toxicology assay chip (MetaChip) for high-throughput microscale toxicity analyses
3. High-Performance Quenchometric Oxygen Sensors Based on Fluorinated Xerogels Doped with [Ru(dpp)3]2+
4. The structural origins of superior performance in sol–gel catalysts
5. Tailoring the Catalytic Performance of Sol–Gel-Encapsulated Tetra-n-propylammonium Perruthenate (TPAP) in Aerobic Oxidation of Alcohols