Catalytic Activity of a Series of Zn(II) Phenoxides for the Copolymerization of Epoxides and Carbon Dioxide

Author:

Darensbourg Donald J.1,Holtcamp Matthew W.1,Struck Ginette E.1,Zimmer Marc S.1,Niezgoda Sharon A.1,Rainey Patrick1,Robertson Jeffrey B.1,Draper Jennifer D.1,Reibenspies Joseph H.1

Affiliation:

1. Contribution from the Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference40 articles.

1. Copolymerization of carbon dioxide and epoxide

2. A brief review covering this and related work has appeared:  Inoue, S.CarbonDioxide as a Source of Carbon; Aresta, M., Forti, G., Eds.; Reidel Publishing Co.  Dordrecht, 1987; p 331. See also an earlier, more comprehensive review:  Rokicki, A.; Kuran, W.J. Macromol. Sci., Rev. Macromol. Chem.1981,C21, 135. An excellent current assessment of the status of catalysts for copolymerization processes utilizing CO2as a monomer has been published:  Super, M. S.; Beckman, E. J.Trends Polym. Sci.1997,5, 236.

3. Diethylzinc-Dihydric Phenol System as Catalyst for the Copolymerization of Carbon Dioxide with Propylene Oxide

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