Substituent Effects on Electrophilic Catalysis by the Carbonyl Group: Anatomy of the Rate Acceleration for PLP-Catalyzed Deprotonation of Glycine
Author:
Affiliation:
1. Departamento de Química Física, Facultad de Química, Universidad de Santiago, 15782 Santiago de Compostela, Spain
2. Department of Chemistry, University at Buffalo, SUNY, Buffalo, New York 14260, United States
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja110795m
Reference56 articles.
1. Biological Enolates: Generation and Stability of the Enolate of N-Protonated Glycine Methyl Ester in Water
2. Formation and Stability of Organic Zwitterions in Aqueous Solution: Enolates of the Amino Acid Glycine and Its Derivatives
3. Formation and Stability of Peptide Enolates in Aqueous Solution
4. On the importance of being zwitterionic: enzymatic catalysis of decarboxylation and deprotonation of cationic carbon
5. Pyridoxal phosphate-dependent enzymes
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