Chelation-Controlled Additions to α-Silyloxy Aldehydes: An Autocatalytic Approach
Author:
Affiliation:
1. P. Roy and Diana T. Vagelos Laboratories, University of Pennsylvania, Department of Chemistry, 231 South 34th Street, Philadelphia, Pennsylvania 19104-6323, United States
Funder
NSF Office of the Director
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol4030259
Reference50 articles.
1. On spontaneous asymmetric synthesis
2. aSoai, K.; Kawasaki, T.; Shibata, T.InCatalytic Asymmetric Synthesis,3rd ed.Ojima, I., Ed.John Wiley & Sons, Inc.:Hoboken, NJ, 2010; pp891–930.
3. bWalsh, P. J.; Kozlowski, M. C.Fundamentals of Asymmetric Catalysis;University Science Books:Sausalito, CA, 2008; pp357–361.
4. Mechanisms of Autocatalysis
5. Asymmetric self-catalytic reaction. Self-production of chiral 1-(3-pyridyl)alkanols as chiral self-catalysts in the enantioselective addition of dialkylzinc reagents to pyridine-3-carbaldehyde
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