Four-Electron-Donor Hemilabile η3-PPh3 Ligand that Binds through a C═C Bond Rather than an Agostic C−H Interaction, and Displacement of the C═C by Methyl Iodide or Water
Author:
Affiliation:
1. Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973-5000, and Chemical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, K2-57, Richland, Washington 99352
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om800401d
Reference98 articles.
1. IR Flash Kinetic Spectroscopy of C-H Bond Activation of Cyclohexane-d0 and -d12 by Cp*Rh(CO)2 in Liquid Rare Gases: Kinetics, Thermodynamics, and Unusual Isotope Effect
2. Activation of the C-H Bonds in Neopentane and Neopentane-d12 by (.eta.5-C5(CH3)5)Rh(CO)2: Spectroscopic and Temporal Resolution of Rhodium-Krypton and Rhodium-Alkane Complex Intermediates
3. The Effect of Alkane Structure on Rates of Photoinduced C−H Bond Activation by Cp*Rh(CO)2 in Liquid Rare Gas Media: An Infrared Flash Kinetics Study
4. Hemilability of Hybrid Ligands and the Coordination Chemistry of Oxazoline-Based Systems
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