Coordination and Reductive Chemistry of Tetraphenylborate Complexes of Trivalent Rare Earth Metallocene Cations, [(C5Me5)2Ln][(μ-Ph)2BPh2]
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697-2025, United States
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic2000409
Reference72 articles.
1. Unsolvated Lanthanide Metallocene Cations [(C5Me5)2Ln][BPh4]: Multiple Syntheses, Structural Characterization, and Reactivity Including the Formation of (C5Me5)3Nd1
2. C-H bond activation through steric crowding of normally inert ligands in the sterically crowded gadolinium and yttrium (C5Me5)3M complexes
3. Multiple Syntheses of (C5Me5)3U
4. Synthesis and Comparative η1-Alkyl and Sterically Induced Reduction Reactivity of (C5Me5)3Ln Complexes of La, Ce, Pr, Nd, and Sm
5. Synthetic Utility of [(C5Me5)2Ln][(μ-Ph)2BPh2] in Accessing [(C5Me5)2LnR]x Unsolvated Alkyl Lanthanide Metallocenes, Complexes with High C−H Activation Reactivity
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