Reaction of a Tungsten Alkylidyne Complex with a Chelating Diphosphine. α-Hydrogen Migration in the Intermediates and Formation of an Alkyl Alkylidene Alkylidyne Complex
Author:
Affiliation:
1. Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996-1600
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om8010917
Reference35 articles.
1. Tungsten Alkyl Alkylidyne and Bis-alkylidene Complexes. Preparation and Kinetic and Thermodynamic Studies of Their Unusual Exchanges
2. Preparation of Tungsten Alkyl Alkylidene Alkylidyne Complexes and Kinetic Studies of Their Formation
3. Multiple metal-carbon bonds. 12. Tungsten and molybdenum neopentylidyne and some tungsten neopentylidene complexes
4. Crystal structure and molecular geometry of W(.tplbond.CCMe3)(:CHCMe3)(CH2CMe3)(dmpe), a mononuclear tungsten(VI) complex with metal-alkylidyne, metal-alkylidene, and metal-alkyl linkages
5. Reactivity of Terminal, Electrophilic Phosphinidene Complexes of Molybdenum and Tungsten. Nucleophilic Addition at Phosphorus and P−P Bond Forming Reactions with Phosphines and Diphosphines
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