A Tungsten Complex with a Bidentate, Hemilabile N-Heterocyclic Carbene Ligand, Facile Displacement of the Weakly Bound W−(CC) Bond, and the Vulnerability of the NHC Ligand toward Catalyst Deactivation during Ketone Hydrogenation
Author:
Affiliation:
1. Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973-5000, and Chemical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, K2-57, Richland, Washington 99352
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om700694e
Reference99 articles.
1. (a) Chaloner, P. A.; Esteruelas, M. A.; Joó, F.; Oro, L. A.Homogeneous Hydrogenation; Kluwer Academic Publishers: Boston, 1994.
2. Catalytic Ionic Hydrogenations
3. Homogeneous Catalysis with Inexpensive Metals: Ionic Hydrogenation of Ketones with Molybdenum and Tungsten Catalysts
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