Heterobimetallic, Cubane-like Mo3S4M‘ Cluster Cores Containing the Noble Metals M‘ = Ru, Os, Rh, Ir. Unprecedented Tri(μ-carbonyl) Bridge Between Ruthenium Atoms in [{(η5-Cp‘)3Mo3S4Ru}2(μ-CO)3]2+
Author:
Affiliation:
1. Haldor Topsøe A/S, Nymøllevej 55, DK-2800 Lyngby, Denmark, and Dipartimento di Chimica “G. Ciamician”, University of Bologna, Via Selmi 2, I-40126 Bologna, Italy
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic001129c
Reference43 articles.
1. New Heterometallic Cubane-Like Clusters [{(η5-Cp)Mo}3S4{M‘(CO)3}](pts) (M‘ = Cr, Mo, W; pts = p-Toluenesulfonate) Obtained by Ligand Substitution Reactions and Insertion of {M‘(CO)3} Fragments
2. Preparation and properties of the heterometallic cuboidal complex [Mo3CrS4(H2O)12]4+: comparisons with [Mo4S4(H2O)12]4+
3. Solution properties and reactivity of the aqua ion of the trimolybdenum(IV) incomplete cuboidal Mo/S cluster nonaaquatetrasulfidotrimolybdenum(4+)
4. Cubane-type Mo3FeS44+ aqua ion and x-ray structure of [Mo3FeS4(NH3)9(H2O)]Cl4
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