β-Hydrogen-Containing Zirconium Alkyls with the Doubly-Bridged Bis(dimethylsilanediyl)dicyclopentadienyl Ligand. X-ray Molecular Structures of [Zr{(SiMe2)2(η5-C5H3)2}ClEt] and [Zr{(SiMe2)2(η5-C5H3)2}Et]2(μ-CH2CH2)-Reference-Cited by-同舟云学术

β-Hydrogen-Containing Zirconium Alkyls with the Doubly-Bridged Bis(dimethylsilanediyl)dicyclopentadienyl Ligand. X-ray Molecular Structures of [Zr{(SiMe2)2(η5-C5H3)2}ClEt] and [Zr{(SiMe2)2(η5-C5H3)2}Et]2(μ-CH2CH2)

Published:1997-04-01 Issue:8 Volume:16 Page:1553-1561
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Fernández Francisco J.¹,Gómez-Sal Pilar¹,Manzanero Antonio¹,Royo Pascual¹,Jacobsen Heiko¹,Berke Heinz¹

Affiliation:

1. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Alcalá de Henares, 28871-Alcalá de Henares, Spain, and Anorganisch Chemisches Institut der Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9610509

Reference50 articles.

1. Organometallic compounds of Group III. Part 41. Direct observation of the initial insertion of an unsaturated hydrocarbon into the titanium-carbon bond of the soluble Ziegler polymerization catalyst Cp2TiCl2-MeAlCl2

2. Ethylene polymerization by a cationic dicyclopentadienyl zirconium(IV) alkyl complex

3. .beta.-Agostic interactions in (C5H4Me)2Zr(CH2CH2R)(PMe3)+ complexes

4. Base-free cationic zirconium benzyl complexes as highly active polymerization catalysts

5. Cation-like homogeneous olefin polymerization catalysts based upon zirconocene alkyls and tris(pentafluorophenyl)borane

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