Realization of Complete Regiochemical Control during the Conversion of Squarate Esters into Complex Linear and Angular Polyquinanes. The Consequences of Incorporating a Leaving Group into One of the Alkenyllithium Reactants-Reference-Cited by-同舟云学术

Realization of Complete Regiochemical Control during the Conversion of Squarate Esters into Complex Linear and Angular Polyquinanes. The Consequences of Incorporating a Leaving Group into One of the Alkenyllithium Reactants

Published:1997-03-01 Issue:6 Volume:62 Page:1723-1729
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Paquette Leo A.¹,Doyon Julien¹

Affiliation:

1. Evans Chemical Laboratories, The Ohio State University, Columbus, Ohio 43210

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo962181m

Reference23 articles.

1. Direct elaboration of complex polyquinanes through twofold addition of vinyl anions to squarate esters

2. The Squarate Ester-1,3,5,7-Octatetraene-Polyquinane Cascade: Reaction Efficiency Is Intimately Linked to the Locus of Substitution within the Vinyl Anion

3. Successive electrocyclic rearrangements initiated by the addition of a lithiated cyclopropenone acetal to a squarate ester

4. The Squarate Ester−Polyquinane Connection. An Analysis of the Capacity of Achiral Divinyl Adducts To Rearrange Spontaneously to Polycyclic Networks Housing Multiple Stereogenic Centers

5. Acetylide anions exert complete control over aldolization during the direct conversion of squarate esters into polyquinanes

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