Stepwise Bromination of Two Acetylene Molecules on a Butterfly-Type Tetrairon Core and Reactivity of the Resulting Bromoacetylene Fragment toward Nucleophiles
Author:
Affiliation:
1. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja047569a
Reference14 articles.
1. Reductive Coupling of Carbonyl Ligands on a Cubane-Type Tetrairon Cluster [Cp4Fe4(CO)4] or [(MeC5H4)4Fe4(CO)4] To Give an Acetylene-Coordinated Cluster [Cp4Fe4(HC⋮CH)2] or [(MeC5H4)4Fe4(HC⋮CH)2]
2. Synthesis and Structures of One- and Two-Electron Oxidized Forms of Bis(acetylene)tetrairon Clusters Cp‘4Fe4(HCCH)2 (Cp‘ = Cp, η5-C5H4Me)
3. Reversible Cleavage and Recombination of an Acetylenic Carbon−Carbon Bond on a Tetrairon Cluster Coupled with a Two-Electron Redox Reaction
4. (b) Patai, S.Supplement C2: The Chemistry ofTriple-bonded Functional Groups; John Wiley & Sons: New York, 1991; Chapter 6.
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