Mononuclear Nickel(III) and Nickel(II) Thiolate Complexes with Intramolecular S−H Proton Interacting with Both Sulfur and Nickel: Relevance to the [NiFe]/[NiFeSe] Hydrogenases
Author:
Affiliation:
1. Contribution from the Department of Chemistry, National Tsing Hua University, Hsinchu 30043, Taiwan; Department of Physics, National Dong Hwa University, Hualien, Taiwan; and Instrumentation Center, National Taiwan University, Taipei, Taiwan
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja048568l
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1. 17O ENDOR Detection of a Solvent-Derived Ni−(OHx)−Fe Bridge That Is Lost upon Activation of the Hydrogenase from Desulfovibrio gigas
2. Crystal structure of the nickel–iron hydrogenase from Desulfovibrio gigas
3. The crystal structure of a reduced [NiFeSe] hydrogenase provides an image of the activated catalytic center
4. Biological activition of hydrogen
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