Scalable Synthesis of 6-Chloro-1H-pyrazolo[3,4-b]pyrazine via a Continuous Flow Formylation/Hydrazine Cyclization Cascade

Author:

Bass Thomas M.1,Zell Daniel1ORCID,Kelly Sean M.1ORCID,Malig Thomas C.2ORCID,Napolitano José G.2ORCID,Sirois Lauren E.1ORCID,Han Chong1ORCID,Gosselin Francis1ORCID

Affiliation:

1. Department of Synthetic Molecule Process Chemistry and, Genentech, Inc., 1 DNA Way, South San Francisco, California 94080, United States

2. Department of Synthetic Molecule Analytical Chemistry, Genentech, Inc., 1 DNA Way, South San Francisco, California 94080, United States

Publisher

American Chemical Society (ACS)

Reference50 articles.

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2. Recent Advances of SHP2 Inhibitors in Cancer Therapy: Current Development and Clinical Application

3. Study to Evaluate the Safety, Pharmacokinetics, and Activity of GDC-1971 in Combination With Either Osimertinib in Participants With Unresectable, Locally Advanced, or Metastatic Non-Small Cell Lung Cancer, or With Cetuximab in Participants With Metastatic Colorectal Cancer, NCT05954871, https://classic.clinicaltrials.gov/ct2/show/NCT05954871?term=GDC-1971&draw=2&rank=2.

4. A Study to Evaluate the Safety, Pharmacokinetics, and Activity of GDC-1971 in Combination With Atezolizumab in Participants With Locally Advanced or Metastatic Solid Tumors, NCT05487235, https://classic.clinicaltrials.gov/ct2/show/NCT05487235?term=GDC-1971&draw=2&rank=1.

5. A Phase Ia/Ib Dose-Escalation and Dose-Expansion Study Evaluating the Safety, Pharmacokinetics, and Activity of GDC-6036 as a Single Agent and in Combination With Other Anti-cancer Therapies in Patients With Advanced or Metastatic Solid Tumors With a KRAS G12C Mutation, NCT04449874, https://classic.clinicaltrials.gov/ct2/show/NCT04449874.

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