Development of a Mild and Efficient Process for Ir-Catalyzed <i>N</i>-Alkylation of 4-Bromopyridin-2-amine with a Primary Alcohol via Borrowing Hydrogen-Reference-Cited by-同舟云学术

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Development of a Mild and Efficient Process for Ir-Catalyzed N-Alkylation of 4-Bromopyridin-2-amine with a Primary Alcohol via Borrowing Hydrogen

Published:2024-07-25 Issue:8 Volume:28 Page:3414-3422
ISSN:1083-6160
Container-title:Organic Process Research & Development
language:en
Short-container-title:Org. Process Res. Dev.

Author:

Nimmagadda Sri Krishna¹,Kalidindi Srinivas¹^ORCID,Bondigela Siva Sankar¹,Korapati Satish¹,Dasgupta Debottam¹,Malik Noormohamed Abdul¹,Rao Prakasa¹,Maity Prantik¹,Coombs John R.²,Hay Michael²^ORCID,Simmons Eric M.²^ORCID,Mukherjee Sabuj¹,Vaidyanathan Rajappa¹,Eastgate Martin D.²^ORCID,González-Bobes Francisco²^ORCID

Affiliation:

1. Chemical Development & API Supply, Biocon Bristol-Myers Squibb Research and Development Center, Biocon Park, Jigani Link Road, Bommasandra IV, Bangalore 560099, India

2. Chemical & Process Development, Bristol Myers Squibb, 1 Squibb Drive, New Brunswick, New Jersey 08903, United States

Publisher

American Chemical Society (ACS)

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.oprd.4c00269

Reference73 articles.

1. Borrowing Hydrogen in the Activation of Alcohols

2. Hydrogen Autotransfer in the N-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

3. Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

4. The Catalytic Amination of Alcohols

5. Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

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