Synthesis and Characterization of the First Niobocene Germyl Complexes and Reactivity of Triphenylsilyl-, Triphenylgermyl-, and Triphenylstannylniobocene Derivatives. X-ray Molecular Structures of d0 Nb(η5-C5H4SiMe3)2(H)2(EPh3) (E = Ge, Sn)-Reference-Cited by-同舟云学术

Synthesis and Characterization of the First Niobocene Germyl Complexes and Reactivity of Triphenylsilyl-, Triphenylgermyl-, and Triphenylstannylniobocene Derivatives. X-ray Molecular Structures of d0 Nb(η5-C5H4SiMe3)2(H)2(EPh3) (E = Ge, Sn)

Published:1998-03-15 Issue:8 Volume:17 Page:1523-1529
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Antiñolo A.¹,Carrillo-Hermosilla F.¹,Castel A.¹,Fajardo M.¹,Fernández-Baeza J.¹,Lanfranchi M.¹,Otero A.¹,Pellinghelli M. A.¹,Rima G.¹,Satgé J.¹,Villaseñor E.¹

Affiliation:

1. Departamento de Química Inorgánica, Orgánica y Bioquímica, Universidad de Castilla-La Mancha, Campus Universitario de Ciudad Real, 13071 Ciudad Real, Spain, Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, 28871 Alcalá de Henares, Spain, Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Università degli Studi di Parma, Centro di Studio per la Strutturistica Diffractometrica del CNR, Viale delle Scienze 78, 43100 Parma, Italy, and...

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om971001b

Reference38 articles.

1. Reactions of carbon monoxide with trimethylsilyl and tris(trimethylsilyl)silyl derivatives of Group 4 metals. Synthesis, characterization, and reactivity of silaacyl complexes

2. Selected references: (a) Tilley, T. D.Inorg. Chem.1990,10, 37. (b) Harrod, J. F.; Mu, Y.; Samuel, E.Polyhedron1991,11, 1239. (c) Corey, J.Advances in Silicon Chemistry; Larson, G., Ed.; JAI Press: Greenwich, CT, 1991; Vol. 1, p 327.

3. Carbon-hydrogen activation. Synthesis of silyl derivatives of niobocene and tantalocene hydrides, their H/D exchange reactions with benzene-d6 and the structure of Cp2Ta(H)2SiMe2Ph

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