A Convenient Synthetic Strategy toward Heavy Alkali Metal Bis(trimethylsilyl)phosphides:  Crystal Structures of the Ladder-Type Polymers [A(thf)P(SiMe3)2]∞ (A = K, Rb, Cs)

Author:

Englich Ulrich1,Hassler Karl1,Ruhlandt-Senge Karin1,Uhlig Frank1

Affiliation:

1. Contribution from the Department of Chemistry, 1-014 Center for Science and Technology, Syracuse University, Syracuse, New York 13244-4100, Institut für Anorganische Chemie II, Universität Dortmund, Otto-Hahn-Strasse 6, D-44221 Dortmund, Germany, and Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, A-8010 Graz, Austria

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference39 articles.

1. Monolithinierte Silylphosphane

2. Silylphosphanes

3. See for example:  (a) Karsch, H. H.; Bienlein, F.; Rupprich, T.; Uhlig, F.; Herrmann, E.; Scheer, M. InHerrmann/Brauer Synthetic Methods ofOrganometallic andInorganic Chemistry; Karsch, H. H., Ed.; G. Thieme Verlag:  Stuttgart, Germany, 1996; Vol. 3, pp 58 ff. (b) Becker, G.; Becker, W.; Mundt, O.Phophorus Sulfur1983,14, 267. (c) Appel, R, Knoll, F.; Ruppert, I.Angew. Chem.1981,93, 771. (d) Becker, G.; Becker, W.; Knebl, R.; Schmidt, H.; Weeber, U.; Westerhausen, M.Phosphorus Sulfur1987,30, 349. (e) Regitz, M.; Binger, P.Angew. Chem.1988,100, 1541.

4. X-Ray Structural Analyses of Organolithium Compounds

5. Bis(trimethylsilyl)phosphidometal complexes

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