Design and Scale-Up of a Practical Enantioselective Route to 5-Phenylbicyclo[2.2.2]oct-5-en-2-one
Author:
Affiliation:
1. Process Research Chemistry, Actelion Pharmaceuticals Ltd., Gewerbestrasse 16, CH-4123 Allschwil, Switzerland
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/op200305y
Reference73 articles.
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2. Stereomutation of 7-tropylionorbornane, 2-tropyliobicyclo[2.2.2]octane, and 2-tropylioadamantane: evidence for the intermediacy of heptafulvenes
3. cHilpert, K; Hubler, F; Renneberg, D.PCT Int. Appl. WO/2008/132679, 2008.
4. Design and Scale-Up of Diels–Alder Reactions for the Practical Synthesis of 5-Phenylbicyclo[2.2.2]oct-5-en-2-one
5. bAbele, S.; Stoessel, F.Safety Assessment of Diels−Alder Reactions with Highly Reactive Reagents.Org. Process Res. Dev,2012. Manuscript in preparation.
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