Understanding the Preference for the Coplanarity of Alkenyl and Carbonyl Ligands in η1-Alkenyl Transition-Metal Complexes: A Simple Molecular Orbital Approach and ab Initio Calculations
Author:
Affiliation:
1. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om9803669
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1. Reactions of Cationic Palladium(II) Methyl and Vinyl Complexes with Alkynes
2. Selective hydrogenation of 1-alkynes to alkenes catalyzed by an iron(II) cis-hydride .eta.2-dihydrogen complex. A case of intramolecular reaction between .eta.2-H2 and .sigma.-vinyl ligands
3. Mechanistic Study of Ruthenium-Catalyzed Hydrosilation of 1-(Trimethylsilyl)-1-buten-3-yne
4. Fünf‐ und sechsfach koordinierte Vinylruthenium‐ und ‐osmium‐Komplexe durch Alkin‐Insertion in Hydridometall‐Vorstufen
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