Kinetics of Proton Transfer from Benzoylnitromethane and 1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance, Inductive, Solvation, Steric, and Transition State Hydrogen-Bonding Effects on Intrinsic Rate Constants-Reference-Cited by-同舟云学术

Kinetics of Proton Transfer from Benzoylnitromethane and 1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance, Inductive, Solvation, Steric, and Transition State Hydrogen-Bonding Effects on Intrinsic Rate Constants

Published:1997-11-01 Issue:23 Volume:62 Page:8162-8170
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Bernasconi Claude F.¹,Montañez Robert L.¹

Affiliation:

1. Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo971259b

Reference39 articles.

1. Intrinsic barriers of reactions and the principle of nonperfect synchronization

2. Kinetics of ionization of nitromethane and phenylnitromethane by amines and carboxylate ions in Me2SO-water mixtures. Evidence of ammonium ion-nitronate ion hydrogen bonded complex formation in Me2SO-rich solvent mixtures

3. Rates of deprotonation of (4-nitrophenyl)acetonitrile and (2,4-dinitrophenyl)acetonitrile in 50% dimethyl sulfoxide-50% water

4. Kinetics of Proton Transfer from 2-Nitro-4-X-phenylacetonitriles to Piperidine and Morpholine in Aqueous Me2SO. Solvent and Substituent Effects on Intrinsic Rate Constants. Transition State Imbalances

5. The low intrinsic reactivity of picrylacetone: an index for the π-acceptor capability of a 2,4,6-trinitrophenyl structure

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