Cyclohexenone Construction by Intramolecular Alkylidene C−H Insertion: Synthesis of (+)-Cassiol-Reference-Cited by-同舟云学术

Cyclohexenone Construction by Intramolecular Alkylidene C−H Insertion: Synthesis of (+)-Cassiol

Published:1996-01-01 Issue:17 Volume:61 Page:5723-5728
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Taber Douglass F.¹,Meagley Robert P.¹,Doren Douglas J.¹

Affiliation:

1. Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo960973a

Reference19 articles.

1. Intramolecular carbon-hydrogen insertions of alkylidenecarbenes. I. Selectivity

2. Demonstration of the Synthetic Power of Oxazaborolidine-Catalyzed Enantioselective Diels-Alder Reactions by Very Efficient Routes to Cassiol and Gibberellic Acid

3. (a) Geometries were optimized at the Hartree−Fock level (restricted for the singlet, unrestricted for the triplet) with the 6-31G** basis set. Single-point energies were calculated at the MP2 (frozen core) level. Hybridization was analyzed by the natural bond orbital method.

4. Vinylidene: the final chapter?

5. Diastereocontrol for Highly Enantioselective Carbon-Hydrogen Insertion Reactions of Cycloalkyl Diazoacetates

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