Complexes of CO2, COS, and CS2 with the Super Lewis Acid BH4+ Contrasted with Extremely Weak Complexations with BH3: Theoretical Calculations and Experimental Relevance1
Author:
Affiliation:
1. Contribution from the Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, California 90089-1661
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja991171a
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1. Electrophilic reactions at single bonds. VII. Hydrogen-deuterium exchange accompanying protolysis (deuterolysis) of borohydride and aluminum hydride anions with anhydrous strong acids. Intermediacy of pentahydroboron and pentahydroaluminum and their structural relation with the methonium ion
2. The structure and stability of BH5. Does correlation make it a stable molecule? Qualitative changes at high levels of theory
3. Effective and Mild Ionic Hydrogenation of Carbon Monoxide, Carbon Dioxide, Methyl Alcohol, Formic Acid, Carbonyl Sulfide and Carbon Disulfide to Methane with Sodium Borohydride/Trifluoromethanesulfonic (triflic) Acid1
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