Catalytic, Highly Enantioselective Friedel−Crafts Reactions of Aromatic and Heteroaromatic Compounds to Trifluoropyruvate. A Simple Approach for the Formation of Optically Active Aromatic and Heteroaromatic Hydroxy Trifluoromethyl Esters
Author:
Affiliation:
1. Center for Metal Catalyzed Reactions, Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo001176m
Reference14 articles.
1. See e.g. (a) Olah, G. A.; Khrisnamurti, R.; Surya Prakash, G. K.Comprehensive Organic Synthesis, 1st ed.; Pergamon: Oxford, 1991; Vol 3, pp 293−339. (b) Roberts, R. M.; Khalaf, A. A.Friedel−Crafts AlkylationChemistry. A Century of Discovery; Marcel Dekker: New York, 1984.
2. Asymmetric Catalysis of the Friedel−Crafts Reaction with Fluoral by Chiral Binaphthol-Derived Titanium Catalysts through Asymmetric Activation
3. Chiral Friedel-Crafts Alkylation of Aromatic Compounds Using Chiral Episulfonium Ions as Carbon Electrophiles
4. Asymmetric Friedel–Crafts reactions of vinyl ethers with fluoral catalyzed by chiral binaphthol-derived titanium catalysts
5. Asymmetric electrophilic substitution on phenols. Enantioselective ortho-hydroxyalkylation mediated by chiral alkoxyaluminum chlorides
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