Unraveling Structure−Reactivity Relationships in SNV Reactions: Kinetics of the Reactions of Methoxybenzylidenemalononitrile, 2-(Methylthiobenzylidene)-1,3-indandione, 2-(Benzylthiobenzylidene)-1,3-indandione, and Methyl β-Methylthio-α-nitrocinnamate with OH- and Thiolate Ions in Aqueous DMSO-Reference-Cited by-同舟云学术

Unraveling Structure−Reactivity Relationships in SNV Reactions: Kinetics of the Reactions of Methoxybenzylidenemalononitrile, 2-(Methylthiobenzylidene)-1,3-indandione, 2-(Benzylthiobenzylidene)-1,3-indandione, and Methyl β-Methylthio-α-nitrocinnamate with OH- and Thiolate Ions in Aqueous DMSO

Published:2001-02-14 Issue:10 Volume:123 Page:2155-2164
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Bernasconi Claude F.¹,Ketner Rodney J.¹,Ragains Mark L.¹,Chen Xin¹,Rappoport Zvi¹

Affiliation:

1. Contribution from the Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064, and the Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja003536t

Reference39 articles.

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2. Kinetic Analysis of Elementary Steps in Nucleophilic Vinylic Substitution Reactions of .alpha.-Nitro-.beta.-X-stilbenes (X = OCH2CF3, OCH3, NO2) with Various Nucleophiles. Detection of the Intermediate in the Reaction of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene with HOCH2CH2S- and of .beta.-Methoxy-.alpha.-nitrostilbene with CF3CH2O-

3. The CF3CH2O- Adducts of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene and .beta.-Methoxy-.alpha.-nitrostilbene, and the MeO- Adducts of .beta.-Methoxy-.alpha.-nitrostilbene. Kinetics of Competition between Protonation and Acid Catalyzed Alkoxide Ion Departure

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