Variable-Temperature Kinetic Analysis of a Three-Site Terminal Ligand Exchange in Nickel A-Frames by Quantitative 31P{1H} EXSY NMR
Author:
Affiliation:
1. Department of Chemistry, Purdue University, 1393 Brown Laboratory of Chemistry, West Lafayette, Indiana 47907-1393
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om980556j
Reference74 articles.
1. Bimetallic systems. Part 21. Synthesis of vinylidene- and phenylene-bridged complexes of dinickel(II), nickel(II)–palladium(II), and nickel(II)-platinum(II) containing Ph2PCH2PPh2(dppm): crystal structures of [(SCN)Ni(µ-dppm)2(µ-CCH2)Ni(NCS)] and [ClPd(µ-dppm)2(µ-CCCl2)NiCl]
2. Syntheses of vinylidene-bridged A-frame palladium complexes containing Ph2PCH2PPh2 or Ph2PCHMePPh2: protonation to give carbyne-bridged complexes
3. A fluxional binuclear nickel(I) complex and evidence for reversible A-frame formation
4. Synthesis and Structures of the μ-Vinylidene Binuclear Nickel Complexes [Ni2(μ-CCH2)(dmpm)2Cl2] and [Ni2(μ-CCH2)(dppm)2Br2]: Comparison of the Electronic Structures of Nickel A-Frames
5. Synthesis and characterization of bis[.mu.-[bis(diphenylphosphino)methane]]-.mu.-methylene-dichlorodiplatinum and related complexes. Insertion of methylene into a platinum-platinum bond
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