Entropic Intermediates and Hidden Rate-Limiting Steps in Seemingly Concerted Cycloadditions. Observation, Prediction, and Origin of an Isotope Effect on Recrossing-Reference-Cited by-同舟云学术

Entropic Intermediates and Hidden Rate-Limiting Steps in Seemingly Concerted Cycloadditions. Observation, Prediction, and Origin of an Isotope Effect on Recrossing

Published:2012-01-18 Issue:4 Volume:134 Page:1914-1917
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Gonzalez-James Ollie M.¹,Kwan Eugene E.¹,Singleton Daniel A.¹

Affiliation:

1. Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842, United States

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja208779k

Reference22 articles.

1. The Activated Complex in Chemical Reactions

2. Some Quantum‐Mechanical Considerations in the Theory of Reactions Involving an Activation Energy

3. Variational transition-state theory

4. Trajectory Studies of SN2 Nucleophilic Substitution. 8. Central Barrier Dynamics for Gas Phase Cl- + CH3Cl

5. Ab Initio Direct Dynamics Study of Cyclopropyl Radical Ring-Opening

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