High Enantioselectivity in Rhodium-Catalyzed Allylic Alkylation of 1-Substituted 2-Propenyl Acetates

Author:

Hayashi Tamio1,Okada Atsushi1,Suzuka Toshimasa1,Kawatsura Motoi1

Affiliation:

1. Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference29 articles.

1. For reviews:  (a) Trost, B. M.; Chulbom, L. InCatalytic Asymmetric Synthesis, 2nd ed.; Ojima, I., Ed.; VCH:  New York, 2000; p 593. (b) Pfaltz, A.; Lautens, M. InComprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer:  Berlin, 1999; Vol. 2, Chapter 24. (c) Trost, B. M.; Van Vranken, D. L.Chem. Rev.1996,96, 395. (d) Hayashi, T. InCatalytic Asymmetric Synthesis; Ojima, I., Ed.; VCH:  New York, 1993; p 325. (e) Frost, C. G.; Howarth, J.; Williams, J. M. J.Tetrahedron:  Asymmetry1992,3, 1089.

2. Asymmetric Molybdenum-Catalyzed Alkylations

3. Enantioselective Molybdenum-Catalyzed Allylic Alkylation Using Chiral Bisoxazoline Ligands

4. Asymmetric molybdenum(0)-catalyzed allylic substitution

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