Cobalt meso-Tetrakis(N-methyl-4-pyridiniumyl)porphyrin Becomes a Catalyst for the Electroreduction of O2 by Four Electrons When [(NH3)5Os]n+ (n = 2, 3) Groups Are Coordinated to the Porphyrin Ring
Author:
Affiliation:
1. Arthur Amos Noyes Laboratories, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9607189
Reference35 articles.
1. Multiple intramolecular electron transfer in the catalysis of the reduction of dioxygen by cobalt meso-tetrakis(4-pyridyl)porphyrin to which four Ru(NH3)5 groups are coordinated
2. Electrocatalysis of the reduction of molecular oxygen to water by tetraruthenated cobalt meso-tetrakis(4-pyridyl)porphyrin adsorbed on graphite electrodes
3. Electrocatalysis of the reduction of dioxygen by adsorbed cobalt 5,10,15,20-tetraarylporphyrins to which one, two, or three pentaammineruthenium(2+) centers are coordinated
4. New Electrocatalysts for the Four-Electron Reduction of Dioxygen Based on (5,10,15-Tris(pentaammineruthenium(II)-4-cyanophenyl)-20- (1-methylpyridinium-4-yl)porphyrinato)cobalt(II) Immobilized on Graphite Electrodes
5. Electrocatalysts for the four-electron reduction of dioxygen based on adsorbed cobalt tetrapyridylporphyrin molecules linked by aquaammine complexes of ruthenium(II)
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