Kinetic Study on the Substitution of Dimethylacetamide for the Terminal Aqua Ligands in the Trinuclear Chromium(III) Complexes [Cr3(μ3-O)(μ-RCO2)6(H2O)3]+ (R = H, CH3, CH3CH2, CH2Cl, CHCl2, CH3OCH2, (CH3)3C, CH2ClCH2, (CH3CH2)2CH). Elucidation of the Mechanism from the Activation Volumes and the Substituent Effects of Bridging Carboxylate Ligands-Reference-Cited by-同舟云学术

Kinetic Study on the Substitution of Dimethylacetamide for the Terminal Aqua Ligands in the Trinuclear Chromium(III) Complexes [Cr3(μ3-O)(μ-RCO2)6(H2O)3]+ (R = H, CH3, CH3CH2, CH2Cl, CHCl2, CH3OCH2, (CH3)3C, CH2ClCH2, (CH3CH2)2CH). Elucidation of the Mechanism from the Activation Volumes and the Substituent Effects of Bridging Carboxylate Ligands

Published:1998-07-01 Issue:15 Volume:37 Page:3779-3784
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Fujihara Takashi¹,Aonahata Jun¹,Kumakura Shigekazu¹,Nagasawa Akira¹,Murakami Kazuhiro¹,Ito Tasuku¹

Affiliation:

1. Department of Chemistry, Faculty of Science, Saitama University, Urawa, Saitama 338-8570, Japan, Department of Chemistry, Faculty of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, and Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic980001g

Reference44 articles.

1. Kinetics of Formation and Dissociation of [Cr3O(O2CCH3)6(urea)3]+: An Example of Statistically Controlled Kinetics and Equilibrium

2. Crystal Structures of the Isomorphous Prototypic Oxo-Centered Trinuclear Complexes [Cr3O(OOCCH3)6(H2O)3]Cl·6H2O and [Fe3O(OOCCH3)6(H2O)3]Cl·6H2O

3. Crystal structure of μ3-oxo-esakis(μ2-acetate) triaquatrichromium (III) 2,6-dihydroxybenzoate dihydrate

4. Synthesis and characterization of symmetric and unsymmetric oxo-bridged trinuclear chromium benzoate complexes: Crystal and molecular structure of [Cr3O(O2CPh)6(py)3]ClO4

5. Carbon-13 NMR studies of oxo-centered trinuclear chromium(III) complexes of the general formula [Cr3O(O2CR)6(L)3]+ (R = Me, Ph; L = H2O, py)

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