1. Department of Marine Sciences, University of Connecticut, 1080 Shennecossett Road, Groton, Connecticut 06340, St. Croix Watershed Research Station, Science Museum of Minnesota, Marine-on-St. Croix, Minnesota 55047, Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, Massachusetts 02543, and National Center for Ocean Research, Taipei, Taiwan, Republic of China