Correlation between Density Functional Studies and Experimental Data of Three New 19-Electron Metal Sandwich Complexes Containing Amido, Ester, and Thioester Cyclopentadienyl Substituents-Reference-Cited by-同舟云学术

Correlation between Density Functional Studies and Experimental Data of Three New 19-Electron Metal Sandwich Complexes Containing Amido, Ester, and Thioester Cyclopentadienyl Substituents

Published:2008-07-18 Issue:15 Volume:27 Page:3693-3700
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Kahlal Samia¹,Ornelas Cátia¹,Astruc Didier¹,Saillard Jean-Yves¹

Affiliation:

1. Sciences Chimiques de Rennes, UMR CNRS No. 6226, Université de Rennes 1, 35042 Rennes Cedex, France, and Institut des Sciences Moléculaires, UMR CNRS No. 5255, Université de Bordeaux I, 351 Cours de la Libération, 33405 Talence Cedex, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om7012875

Reference48 articles.

1. Design, stabilization, and efficiency of organometallic "electron reservoirs". 19-Electron sandwiches .eta.5-C5R5FeI-.eta.6-C6R'6, a key class active in redox catalysis

2. Novel reactions of dioxygen in organometallic chemistry. Hydrogen atom abstraction vs. dimerization of the 19-electron complexes .eta.5-cyclopentadienyliron(I) .eta.6-arene

3. Syntheses, characterizations, and stereoelectronic stabilization of organometallic electron reservoirs: the 19-electron d7 redox catalysts .eta.5-C5R5Fe-.eta.6-C6R'6

4. Organometallic electron reservoirs. 5. Novel mode of carbon-hydrogen activation using dioxygen via superoxide radical anion in solution and in the solid state with C5R5FeIC6R'6. Subsequent bond formation with carbon, silicon, phosphorus, manganese, iron, chromium, and molybdenum

5. .eta.5-Benzyl: crystal structure, nucleophilic properties, and electron-transfer reactions of CpFe(.eta.5-C6Me5CH2), an intermediate in carbon-hydrogen activation by oxygen via O2-

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