Transformations and Agostic Interactions of Hydrocarbyl Ligands Bonded to the Sulfur-Rich Dimolybdenum Site {Mo2Cp2(μ-SMe)3}:  Chemical and Electrochemical Formation of μ-Alkyl and μ-Vinyl Compounds from a μ-Alkylidene Derivative

Author:

Cabon Nolwenn1,Le Goff Alan1,Le Roy Christine1,Pétillon François Y.1,Schollhammer Philippe1,Talarmin Jean1,McGrady John E.2,Muir Kenneth W.3

Affiliation:

1. UMR CNRS 6521, Chimie, Electrochimie Moléculaires et Chimie Analytique, UFR Sciences et Techniques, Université de Bretagne Occidentale, CS 93837, 29238 Brest-Cedex 3, France

2. Department of Chemistry, University of York, Heslington, York Y010 5DD, U.K.

3. Chemistry Department, University of Glasgow, Glasgow G12 8QQ, U.K.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference49 articles.

1. (b) Braunstein, P.; Rose, J. InChemical Bonds-Better Ways to Make Them andBreak Them; Bernal, I., Ed.; Elsevier:  Amsterdam, 1989; p 5.

2. (c) Hidai, M.; Mizobe, Y. InTransition Metal Sulfur Chemistry-Biological and IndustrialSignificance; Stiefel, E. I., Matsumoto, K., Eds.; ACS Symposium Series 653; American Chemical Society:  Washington, DC, 1996; p 310.

3. Towards novel organic synthesis on multimetallic centres: Syntheses and reactivities of dinuclear ruthenium thiolate complexes

4. A Triply Bonded Dimolybdenum Hydride Complex with Acid, Base and Radical Activity

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