Investigating the α-Effect in Gas-Phase SN2 Reactions of Microsolvated Anions
Author:
Affiliation:
1. Department of Chemistry, University of Copenhagen, Universitetsparken 5, Copenhagen, DK-2100 Denmark
2. Department of Chemistry and Biochemistry, University of Colorado, 215 UCB, Boulder, Colorado 80309, United States
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja4066943
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1. Bridging the gap between the gas phase and solution: transition in the kinetics of nucleophilic displacement reactions
2. Gas-phase measurements of the influence of stepwise solvation on the kinetics of nucleophilic displacement reactions with chloromethane and bromomethane at room temperature
3. Nucleophilic displacement as a function of hydration number and temperature: rate constants and product distributions for OD-(D2O)0,1,2,3 + CH3Cl at 200-500 K
4. Translational Energy Dependence of Cross Sections for Reactions of OH-(H2O)n with CH3Cl and CH3Br
5. Temperature Dependences of the Rate Constants and Branching Ratios for the Reactions of F-(H2O)0-5 with CH3Br
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