Synthesis and Characterization of Double- and Triple-Butterfly Fe/S Cluster Complexes Obtained from the Novel Butterfly Cluster Anions {(μ-RS)(μ-CO)[Fe2(CO)6]2(μ4-S)}- and (μ-RS)(μ-S-)[Fe2(CO)6]3(μ4-S)2. Crystal Structures of (μ-MeS)(μ-PhNHCS)[Fe2(CO)6]2(μ4-S), (μ-MeS)(μ-MeSCS)[Fe2(CO)6]2(μ4-S), and (μ-PhCH2S)2[Fe2(CO)6]3(μ4-S)2-Reference-Cited by-同舟云学术

Synthesis and Characterization of Double- and Triple-Butterfly Fe/S Cluster Complexes Obtained from the Novel Butterfly Cluster Anions {(μ-RS)(μ-CO)[Fe2(CO)6]2(μ4-S)}- and (μ-RS)(μ-S-)[Fe2(CO)6]3(μ4-S)2. Crystal Structures of (μ-MeS)(μ-PhNHCS)[Fe2(CO)6]2(μ4-S), (μ-MeS)(μ-MeSCS)[Fe2(CO)6]2(μ4-S), and (μ-PhCH2S)2[Fe2(CO)6]3(μ4-S)2

Published:2000-08-22 Issue:19 Volume:19 Page:3909-3915
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Song Li-Cheng¹,Hu Qing-Mei¹,Fan Hong-Tao¹,Sun Bao-Wei¹,Tang Ming-Yi¹,Chen Yu¹,Sun Yi¹,Sun Cui-Xiang¹,Wu Qiang-Jin¹

Affiliation:

1. Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China, and State Key Laboratory of Structural Chemistry, Fuzhou 350002, China

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om0002071

Reference36 articles.

1. Novel bridging sulfide anion complexes of the hexacarbonyldiiron unit: a new route to alkylthio complexes of iron

2. Structures of two .mu.-(alkylthio)-.mu.-(alkylmercurithio)-bis(tricarbonyliron) complexes, (.mu.-RS)(.mu.-RHgS)Fe2(CO)6 (R = methyl and ethyl)

3. Addition of alkynyllithium reagents to the sulfur-sulfur bond of (.mu.-dithio)bis(tricarbonyliron): equilibriums between open sulfur-centered and bridged carbon-centered anions

4. Novel boron-to-sulfur alkyl group transfer in reactions of lithium triethylborohydride-derived bis(.mu.-thiolato)bis(tricarbonyliron) dianion with mercuric chloride and alkylmercuric chlorides

5. Chemistry of μ-dithiobis(tricarbonyliron), an inorganic mimic of organic disulfides

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