Discovery of S···C≡N Intramolecular Bonding in a Thiophenylcyanoacrylate-Based Dye: Realizing Charge Transfer Pathways and Dye···TiO2 Anchoring Characteristics for Dye-Sensitized Solar Cells

Author:

Cole Jacqueline M.1234ORCID,Blood-Forsythe Martin A.1,Lin Tze-Chia1,Pattison Philip5,Gong Yun1,Vázquez-Mayagoitia Álvaro3,Waddell Paul G.16,Zhang Lei1,Koumura Nagatoshi7,Mori Shogo8

Affiliation:

1. Cavendish Laboratory, Department of Physics, University of Cambridge, J. J. Thomson Avenue, Cambridge, CB3 0HE, United Kingdom

2. ISIS Neutron and Muon Source, STFC Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX, United Kingdom

3. Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439, United States

4. Department of Chemical Engineering and Biotechnology, University of Cambridge, West Cambridge Site, Philippa Fawcett Drive, Cambridge, CB3 0FS, United Kingdom

5. Swiss Norwegian Beamlines, European Synchrotron Radiation Facility, F-38000 Grenoble, France

6. Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organisation, Lucas Heights NSW 2234, Australia

7. National Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan

8. Division of Chemistry and Materials, Shinshu University, Faculty of Textile Science and Technology, Ueda, Nagano 3868567, Japan

Funder

Royal Commission for the Exhibition of 1851

Australian Nuclear Science and Technology Organisation

Winston Churchill Foundation of the United States

Publisher

American Chemical Society (ACS)

Subject

General Materials Science

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