Glass-Transition and Side-Chain Dynamics in Thin Films: Explaining Dissimilar Free Surface Effects for Polystyrene vs Poly(methyl methacrylate)
Author:
Affiliation:
1. Department of Mechanical Engineering, ‡Department of Civil & Environmental Engineering, and §Department of Materials Science & Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3109, United States
Funder
Dow Chemical Company
Northwestern University
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acsmacrolett.6b00037
Reference51 articles.
1. Size-Dependent Depression of the Glass Transition Temperature in Polymer Films
2. Dynamics near Free Surfaces and the Glass Transition in Thin Polymer Films: A View to the Future
3. Effects of Nanoscale Confinement and Interfaces on the Glass Transition Temperatures of a Series of Poly(n-methacrylate) Films
4. Glass transition and chain mobility in thin polymer films
5. Effects of confinement on material behaviour at the nanometre size scale
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