Soft−Hard Acid−Base Interactions: Probing Coordination Preferences of Sulfur and Selenium in Mixed Chalcophosphates in the Family APbPS4−xSex (A = K, Rb, Cs; x = 0−4)
Author:
Affiliation:
1. Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208
2. Materials Science Division (Bldg. 223), Argonne National Laboratory, 9700 S. Cass Ave., Argonne, Illinois 60439
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic901283k
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1. Synthesis and structures of Na4P2Se6, Cs3PSe4, and Rb4P2Se9
2. A Study of the System Li-P-Se
3. Synthesis in Molten Alkali Metal Polyselenophosphate Fluxes: A New Family of Transition Metal Selenophosphate Compounds, A2MP2Se6 (A = K, Rb, Cs; M = Mn, Fe) and A2M'2P2Se6 (A = K, Cs; M' = Cu, Ag)
4. Use of molten alkali-metal polythiophosphate fluxes for synthesis at intermediate temperatures. Isolation and structural characterization of ABiP2S7 (A = K, Rb)
5. Chemistry in Molten Alkali Metal Polyselenophosphate Fluxes. Influence of Flux Composition on Dimensionality. Layers and Chains in APbPSe4, A4Pb(PSe4)2 (A = Rb, Cs), and K4Eu(PSe4)2
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