Distinguishing the Early and Late Transition States and Exploring the Validity of σ → σ*#, σ# → σ*, and σ → π*CO Concepts in Diastereoselection from NBO Analysis-Reference-Cited by-同舟云学术

Distinguishing the Early and Late Transition States and Exploring the Validity of σ → σ*#, σ# → σ*, and σ → π*CO Concepts in Diastereoselection from NBO Analysis

Published:2006-04-28 Issue:11 Volume:71 Page:4178-4182
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Yadav Veejendra K.¹,Gupta Archana¹,Balamurugan Rengarajan¹,Sriramurthy Vardhineedi¹,Vijaya Kumar Naganabonia¹

Affiliation:

1. Department of Chemistry, Indian Institute of Technology, Kanpur-208016, India

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo060291f

Reference24 articles.

1. Electronic control of .pi.-facial selectivities in nucleophilic additions to 7-norbornanones

2. Hyperconjugation as a stereoinductive factor in the approach of electrophiles to trigonal carbon

3. Stereochemistry of nucleophilic addition to cyclohexanone. The importance of two-electron stabilizing interactions

4. The Exterior Frontier Orbital Extension Model

5. Origin of Facial Diastereoselection. Evidence for Negative Role of Antiperiplanar Hyperconjugation Effects in the Transition State of Carbene Insertion

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