Unusual Me−O Bond Cleavage in a Metalated Crown-Ether: X-ray Molecular Structure of (5-Methoxy-4,6-dimethyl-1,3-xylylene-2-one)-15 Crown-4 Complex of Pentamethylcyclopentadienyl Iridium-Reference-Cited by-同舟云学术

Unusual Me−O Bond Cleavage in a Metalated Crown-Ether: X-ray Molecular Structure of (5-Methoxy-4,6-dimethyl-1,3-xylylene-2-one)-15 Crown-4 Complex of Pentamethylcyclopentadienyl Iridium

Published:1999-02-26 Issue:6 Volume:38 Page:1211-1215
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Amouri H.,Vaissermann J.,Rager M. N.,Besace Y.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic980811s

Reference19 articles.

1. Tilden Lecture. ? 5-Cyclopentadienyl and ? 6-arene as protecting ligands towards platinum metal complexes

2. Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part XII. Tris(solvent) complexes and complexes of η6-benzene, -naphthalene, -phenanthrene, -indene, -indole, and -fluorene and η5-lndenyl and -indolyl

3. Pentamethylcyclopentadienyl-rhodium and -iridium complexes.

4. Cyclopentadienyl- or pentamethylcyclopentadienyl-(arene)cobalt(III) complexes: arene = indole, benzene, mesitylene, hexamethylbenzene, 1,4-dihydroxy- and 1-hydroxy-4-methoxytetramethylbenzene

5. Protonation and methylation of η4-2,3,5,6-tetramethyl-1,4-benzoquinone(η5-pentamethylcyclopentadienyl)cobalt

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