Synthesis, Structure, and Electrochemistry of the Ni–Au Carbonyl Cluster [Ni12Au(CO)24]3– and Its Relation to [Ni32Au6(CO)44]6–
Author:
Affiliation:
1. Dipartimento di Chimica Fisica e Inorganica, Università di Bologna, Viale Risorgimento 4 - 40136 Bologna, Italy
2. Dipartimento di Chimica, Università di Siena, Via De Gasperi 2, Siena, Italy
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic301679h
Reference84 articles.
1. Isostructural [Au6Pd6(Pd6-xNix)Ni20(CO)44]6- and [Au6Ni32(CO)44]6- Clusters Containing Corresponding Nonstoichiometric Au6Pd6(Pd6-xNix)Ni20 and Stoichiometric Au6Ni32 Nanosized Cores: Substitutional Pd/Ni Crystal Disorder (Coloring Problem) at Only Six Specific Nonadjacent Pseudoequivalent Metal Sites in the 38-Atom Trimetallic Close-Packed Framework
2. Synthesis and structural-bonding analysis of the [Au6Ni12(CO)24]2- dianion containing an unprecedented 18-vertex cubic Td metal core composed of five face-fused octahedra: the first example of a discrete gold/nickel bimetallic-bonded species
3. Synthesis and experimental/theoretical investigation of the high-nuclearity cubic Td [Au6Ni12(CO)24]2− cluster, an initial example of a discrete gold-nickel bimetallic-bonded species: comparative analysis of the results of electron-counting methods and the Fenske-Hall MO model in rationalizing the bonding interactions of its Au6Ni12 core consisting of five face-fused metal octahedra
4. Semiconductor Nanocrystals as Fluorescent Biological Labels
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