1. Centre for Ecology and Hydrology, Edinburgh Research Station, Bush Estate, Penicuik, Midlothian, EH26 0QB, U.K., School of Earth, Atmospheric and Environmental Sciences (SEAES), The University of Manchester, Sackville Street, M60 1QD, Manchester, U.K., and Biogeochemistry Department, Max Planck Institute for Chemistry, P.O. Box 3060, 55020 Mainz, Germany, and Energy Research Centre of The Netherlands (ECN), P.O. Box 1, 1755 ZG Petten, The Netherlands