Synthesis of (−)-Lasubine(I) via a Planar Chiral [(η6-arene)Cr(CO)3] Complex

Author:

Ratni Hassen1,Kündig E. Peter1

Affiliation:

1. Department of Organic Chemistry, University of Geneva, 30 Quai Ernest Ansermet, CH-1211 Geneva 4, Switzerland

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference11 articles.

1. Lythraceous alkaloids. X. Alkaloids of Lagerstroemia subcostata and L. favriei: A contribution to the chemotaxonomy.

2. Review:  (a) Golebiewski, W. M.; Wrobel, J. T. InThe Alkaloids; Academic Press:  New York, 1981; Vol. 18, Chapter 4, p 263. Recent reports:  (b) Beckwith, A. L. J.; Joseph, S. P.; Mayadunne, T. A.J. Org. Chem.1993,58, 4198. (c) Pilli, R. A.; Dias, L. C.; Maldaner, A. O.Tetrahedron Lett.1993,34, 2729.(d) Pilli, R. A.; Dias, L. C.; Maldaner, A. O.J. Org. Chem.1995,60, 717. (e) Bardot, V.; Gardette, D.; Gelas-Mialhe, Y.; Gramain, J.C.; Remuson, R.Hetereocycles1998,48, 507.

3. (a) Chalard, P.; Remuson, R.; Mialhe, Y. G.; Remuson, J. C.Tetrahedron:  Assymetry1998,9, 4361.

4. Enantiopure 2,3-dihydro-4-pyridones as synthetic intermediates. Asymmetric syntheses of the quinolizidine alkaloids, (+)-myrtine, (-)-lasubine I, and (+)-subcosine I

5. Planar Chiral Tricarbonylchromium Complexes: Asymmetric Aza-Diels-Alder Reaction and Intramolecular Radical Cyclization to Indolizines and Quinolizidines

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