Unexpected Four-Membered over Six-Membered Ring Formation during the Synthesis of Azaheterocyclic Phosphonates: Experimental and Theoretical Evaluation-Reference-Cited by-同舟云学术

Unexpected Four-Membered over Six-Membered Ring Formation during the Synthesis of Azaheterocyclic Phosphonates: Experimental and Theoretical Evaluation

Published:2006-06-13 Issue:26 Volume:128 Page:8468-8478
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Van Speybroeck Veronique¹,Moonen Kristof¹,Hemelsoet Karen¹,Stevens Christian V.¹,Waroquier Michel¹

Affiliation:

1. Contribution from the Center for Molecular Modeling, Ghent University, Proeftuinstraat 86, B-9000 Ghent, Belgium, and Research Group SynBioC, Department of Organic Chemistry, Faculty of Bioscience Engineering, Ghent University, Coupure links 653, B-9000 Ghent, Belgium

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0584119

Reference61 articles.

1. Smith, M. B.; March, J. Kinetic Requirements for reactions.Advanced Organic Chemistry, 5th ed.; J. Wiley and Sons: New York, 2001; pp 278−282.

2. Ring-closure reactions. 7. Kinetics and activation parameters of lactone formation in the range of 3- to 23-membered rings

3. Ring-closure reactions. 11. The activation parameters for the formation of four- to six-membered lactones from .omega.-bromoalkanoate ions. The role of the entropy factor in small- and common-ring formation

4. 5-Endo-trigonal reactions: a disfavoured ring closure

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