Insertion of One, Two, and Three Molecules of Alkyne into the Pd−C Bond of Ortho-palladated Primary and Secondary Arylalkylamines-Reference-Cited by-同舟云学术

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Insertion of One, Two, and Three Molecules of Alkyne into the Pd−C Bond of Ortho-palladated Primary and Secondary Arylalkylamines

Published:2009-06-16 Issue:14 Volume:28 Page:4175-4195
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Vicente José¹,Saura-Llamas Isabel¹,Turpín Juana¹,Bautista Delia²,de Arellano Carmen Ramírez³,Jones Peter G.⁴

Affiliation:

1. Grupo de Química Organometálica, Departamento de Química Inorgánica, Facultad de Química, Universidad de Murcia, E-30071 Murcia, Spain

2. SAI, Universidad de Murcia, E-30071 Murcia, Spain

3. Departamento de Química Orgánica, Universidad de Valencia, E-46100 Valencia, Spain

4. Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, 38023 Braunschweig, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9002895

Reference145 articles.

1. Reactivity of cyclopalladated complexes. Part 5. Insertion reactions of diphenylacetylene, 1-phenylprop-1-yne, and hexafluorobut-2-yne with cyclopalladated compounds. Crystal and molecular structure of chloro{3–4-η-4-[(2-dimethylaminomethyl)phenyl]-1,4-dimethyl-2,3-diphenylbuta-1,3-dienyl-C1N}palladium(II) and bromo{3–4-η-4-[(2-dimethylaminomethyl)phenyl]-2,4-dimethyl-1,3-diphenylbuta-1,3-dienyl-C1N}-palladium(II)

2. One-pot synthesis of heterocyclic compounds through insertion of alkynes into the PdC bond of activated cyclopalladated benzyl methyl sulphide

3. Palladium-catalyzed annulation of aryl iodides with diphenylacetylene

4. Reaction of cyclopalladated compounds. 15. Controlled synthesis of heterocyclic compounds through ring enlargement by alkyne insertions into the palladium-carbon bonds of cyclopalladated amines followed by ring closure

5. Isoquinolinium salt syntheses from cyclopalladated benzaldimines and alkynes

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