Computational Studies of Pericyclic Reactions between Aminoalanes and Ethyne, Ethene, and Dienes. A Reactive Aminoalane That Should Prefer [2 + 2] and [4 + 2] Cyclizations to Dimerization
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois 60115
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om800515e
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1. σ- and π-Bond Strengths in Main Group 3−5 Compounds
2. π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
3. Multiple Bonding Involving the Heavier Main Group 3 Elements Al, Ga, In, and Tl
4. Pericyclic Reactions between Aminoboranes R2BNR2‘ and Alkenes: [4+2] vs [2+2] Transition States
5. Ab Initio Studies of Pericyclic Reactions of Aminoboranes. [2 + 2] Dimerization and [4 + 2] Diels−Alder Reactions of H2BNH2, Me2BNMe2, and (F3C)2BNMe2
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