Chiral Solvation as a Means to Quantitatively Characterize Preferential Solvation of a Helical Polymer in Mixed Solvents
Author:
Affiliation:
1. Contribution from the Herman F. Mark Polymer Research Institute, Polytechnic University, Brooklyn, New York 11201
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9709637
Reference37 articles.
1. A Helical Polymer with a Cooperative Response to Chiral Information
2. Macromolecular stereochemistry: a cooperative deuterium isotope effect leading to a large optical rotation
3. Macromolecular stereochemistry: helical sense preference in optically active polyisocyanates. Amplification of a conformational equilibrium deuterium isotope effect
4. A macromolecular conformational change driven by a minute chiral solvation energy
5. Reichardt, C.Solvents and Solvent Effects in Organic Chemistry, 2nd ed.; VCH Verlagsgesellschaft: Weinheim, 1988; pp 35−38.
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