Electron Transfer in Mixed-Valence [FeIII2FeIIO(O2CCH3)6(3-Cl-py)3]·3-Cl-py: Effects of a Crystallographic Phase Transition and Conversion of Solvate and Ligand Molecules from Statically Disordered to Dynamically Disordered on the Valence Detrapping
Author:
Affiliation:
1. Department of Chemistry-0358, University of California at San Diego, La Jolla, California 92093-0358, and Institut für Anorganische und Analytische Chemie, Johannes Gutenberg-Universität, D-55099 Mainz, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9700314
Reference44 articles.
1. Micromodulation: induction of intramolecular electron transfer by solvate molecule dynamics in the iron acetato oxo methylpyridine mixed-valence complex [Fe3O(O2CCH3)6(3-Me-py)3](solvate)
2. Subtle effects of solvate molecules on the rate of intramolecular electron transfer of mixed-valence complexes in the solid state
3. Lattice-engineered micromodulation of intramolecular electron-transfer rates in trinuclear mixed-valence iron acetate complexes
4. Deuteron NMR study of lattice dynamics affecting the rate of intramolecular electron transfer in the iron acetato oxo pyridine mixed-valence complex [Fe3O(O2CCH3)6(py)3](py)
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