Origin of Diastereoselectivity in the Synthesis of Chiral Bicyclic Lactams: π-Facial Selective Attack of Singlet Oxygen Induced by Hindered Internal Rotation-Reference-Cited by-同舟云学术

Origin of Diastereoselectivity in the Synthesis of Chiral Bicyclic Lactams: π-Facial Selective Attack of Singlet Oxygen Induced by Hindered Internal Rotation

Published:2007-06-13 Issue:26 Volume:111 Page:5855-5863
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Catak Saron¹,Celik Hasan¹,Demir Ayhan S.¹,Aviyente Viktorya¹

Affiliation:

1. Departments of Chemistry, Bogazici University, 34342 Bebek, Istanbul, Turkey, and Middle East Technical University, 06531 Ankara, Turkey

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp071608y

Reference96 articles.

1. Chiral bicyclic lactams: useful precursors and templates for asymmetric syntheses1

2. Diastereoselective cyclopropanations of chiral bicyclic lactams leading to enantiomerically pure cyclopropanes. Application to the total synthesis of CIS-(1S, 3R)-deltamethrinic acid and R-(-)- dictyopterene C

3. Asymmetric total synthesis of (+)-.DELTA.9(12)-capnellene

4. Tritylallyldimethylsilane−TiCl4 Annulations to Electron Deficient Olefins. Diastereomerically Pure 3-Substituted and 3,4-Disubstituted Cyclopentanols

5. Chiral non-racemic bicyclic lactams. Vehicles for the construction of natural and unnatural products containing quaternary carbon centers.

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